• 文献标题:   Infrared induced repeatable self-healing and removability of mechanically enhanced graphene-epoxy flexible materials
  • 文献类型:   Article
  • 作  者:   GUO YK, ZOU DL, ZHU WQ, YANG XJ, ZHAO PX, CHEN CA, SHUAI MB
  • 作者关键词:  
  • 出版物名称:   RSC ADVANCES
  • ISSN:  
  • 通讯作者地址:   Sci Technol Surface Phys Chem Lab
  • 被引频次:   1
  • DOI:   10.1039/c9ra00261h
  • 出版年:   2019

▎ 摘  要

A repeatable self-healing epoxy composite mechanically enhanced by graphene nanosheets (GNS) was prepared from an epoxy monomer with Diels-Alder (DA) bonds, octanediol glycidyl ether (OGE) and polyether amine (D230). The GNS/epoxy composites, with a maximum tensile modulus of 14.52 +/- 0.45 MPa and elongation at break more than 100%, could be healed several times under Infrared (IR) light with the healing efficiency as high as 90% through the molecule chain mobility and the rebonding of reversible DA bonds between furan and maleimide. Also, they displayed excellent recyclable ability by transforming into a soluble polymer, which offers a wide range of possibilities to produce epoxy flexible materials with healing and removable abilities.