• 文献标题:   Novel sponge-like N-doped graphene film as high-efficiency electrode for Li-ion battery
  • 文献类型:   Article
  • 作  者:   LIU SL, WEI W, WANG YY, REN J
  • 作者关键词:   nitrogen doped graphene, film, loose porous structure, lithiumion battery
  • 出版物名称:   APPLIED SURFACE SCIENCE
  • ISSN:   0169-4332 EI 1873-5584
  • 通讯作者地址:   Shaanxi Univ Sci Technol
  • 被引频次:   4
  • DOI:   10.1016/j.apsusc.2019.04.209
  • 出版年:   2019

▎ 摘  要

The novel sponge-like N-doped reduced graphene oxide films (N-rGO) were synthesized successfully via a facile one-step route at 800 degrees C. The as-prepared films are few-layer and have loose sponge-like structure between layers and the N-doping content can reach to 7.11% and C/O is 17:1. As an anode material of Li-ion battery (LiBs), the as-prepared N-rGO flim exhibit excellent electrochemical properties. It delivers an initial discharge capacity of 1673 mAh g(-1) and the reversible specific discharge capacity of 906 mAh g(-1) at the current density of 100 mA g(-1). Even at the current density of 1.6 A g(-1), the reversible specific capacity still could remain at 346 mAh g(-1) after 500 cycles. The appearance of N-doping microstructure of rGO with a high content and loose sponge-like framework might be applied to explain thus enhanced electrochemical properties.