• 文献标题:   A glassy carbon electrode modified with graphene oxide and silver nanoparticles for amperometric determination of hydrogen peroxide
  • 文献类型:   Article
  • 作  者:   NOOR AM, SHAHID MM, RAMESHKUMAR P, HUANG NM
  • 作者关键词:   cyclic voltammetry, electrochemical impedance spectroscopy, transmission electron microscopy, nyquist plot, electrocatalysi
  • 出版物名称:   MICROCHIMICA ACTA
  • ISSN:   0026-3672 EI 1436-5073
  • 通讯作者地址:   Univ Malaya
  • 被引频次:   34
  • DOI:   10.1007/s00604-015-1679-1
  • 出版年:   2016

▎ 摘  要

The article describes a glassy carbon electrode (GCE) modified with a nanocomposite consisting of graphene oxide and silver nanoparticles, and its application to amperometric determination of hydrogen peroxide (H2O2). Cyclic voltammetry with this modified electrode reveals efficient electrocatalytic reduction of H2O2. The response to H2O2 at a working potential of -0.3 V (vs. Ag/AgCl) is linear in the 100 mu M to 11 mM concentration range at pH 7.2. The limit of detection is 28.3 mu M (at an S/N ratio of 3). Good selectivity is observed over physiological interferents such as dopamine, ascorbic acid, uric acid and glucose.