• 文献标题:   Poly (2,6-dimethyl-1,4-phenylene oxide)/ionic liquid functionalized graphene oxide anion exchange membranes for fuel cells
  • 文献类型:   Article
  • 作  者:   YANG Q, LIN CX, LIU FH, LI L, ZHANG QG, ZHU AM, LIU QL
  • 作者关键词:   imidazoliumfunctionalized graphene oxide, poly 2 6dimethyl1 4phenylene oxide, anion exchange membrane, fuel cell
  • 出版物名称:   JOURNAL OF MEMBRANE SCIENCE
  • ISSN:   0376-7388 EI 1873-3123
  • 通讯作者地址:   Xiamen Univ
  • 被引频次:   24
  • DOI:   10.1016/j.memsci.2018.02.036
  • 出版年:   2018

▎ 摘  要

To improve the overall performance of anion exchange membranes (AEMs) for fuel cells, a series of composite AEMs was prepared via a facile approach using ionic liquid-functionalized graphene oxide (IL-GO) and imidazolium-functionalized poly (2,6-dimethyl-1,4-phenylene oxide) (ImPPO). The prepared ImPPO/IL-GO-0.5% (0.5% refers to the weight percentage of IL-GO) membranes with an ionic exchange capacity (IEC) of 1.9 meq g(-1) achieved a hydroxide conductivity of 78.5 mS cm(-1). The high conductivity of ImPPO/IL-GO-0.5% is due to the fact that the ionic cluster size of composite membranes (3.43-3.58 nm) is larger than that of the pristine membrane (3.30 nm). The ionic cluster morphology is confirmed by atomic force microscopy (AFM) and small angle X-ray scattering (SAXS). Moreover, the AEMs retained approximately 70% of their initial hydroxide conductivity after the alkaline stability test in a 2M aqueous NaOH at 80 degrees C for 480 h, indicating a good alkaline stability. A single cell using ImPPO/IL-GO-0.5% exhibits a peak power density of 136 mW cm(-2) at 60 degrees C under 100% related humidity, thereby having a great potential for fuel cells.