• 文献标题:   Effect of copper surface pre-treatment on the properties of CVD grown graphene
  • 文献类型:   Article
  • 作  者:   KIM MS, WOO JM, GEUM DM, RANI JR, JANG JH
  • 作者关键词:  
  • 出版物名称:   AIP ADVANCES
  • ISSN:   2158-3226
  • 通讯作者地址:   GIST
  • 被引频次:   9
  • DOI:   10.1063/1.4903369
  • 出版年:   2014

▎ 摘  要

Here, we report the synthesis of high quality monolayer graphene on the pre-treated copper (Cu) foil by chemical vapor deposition method. The pre-treatment process, which consists of pre-annealing in a hydrogen ambient, followed by diluted nitric acid etching of Cu foil, helps in removing impurities. These impurities include native copper oxide and rolling lines that act as a nucleation center for multilayer graphene. Raman mapping of our graphene grown on pre-treated Cu foil primarily consisted of similar to 98% a monolayer graphene with as compared to 75 % for the graphene grown on untreated Cu foil. A high hydrogen flow rate during the pre-annealing process resulted in an increased I-2D/IG ratio of graphene up to 3.55. Uniform monolayer graphene was obtained with a I2D/IG ratio and sheet resistance varying from 1.84-3.39 and 1110-1290 Omega/square, respectively. (C) 2014 Author(s).