• 文献标题:   Highly durable graphene nanoplatelets supported Pt nanocatalysts for oxygen reduction
  • 文献类型:   Article
  • 作  者:   SHAO YY, ZHANG S, WANG CM, NIE ZM, LIU J, WANG Y, LIN YH
  • 作者关键词:   graphene nanoplatelet, polymer electrolyte membrane fuel cell, oxygen reduction, durability, carbon nanotube
  • 出版物名称:   JOURNAL OF POWER SOURCES
  • ISSN:   0378-7753 EI 1873-2755
  • 通讯作者地址:   Pacific NW Natl Lab
  • 被引频次:   292
  • DOI:   10.1016/j.jpowsour.2010.02.044
  • 出版年:   2010

▎ 摘  要

We report graphene nanoplatelets (GNPs), which exhibit the advantages of both single-layer graphene and highly graphitic carbon, as a durable alternative support material for Pt nanoparticles for oxygen reduction in fuel cells. Pt nanoparticles are deposited on poly(diallyldimethylammonium chloride) (PDDA)-coated GNP, and characterized with transmission electron microscopy. X-ray diffraction, Raman spectra, and electrochemical tests. Pt/GNP exhibits greatly enhanced electrochemical durability (2-3 times that of Pt/CNT and commercial Etek Pt/C). These are attributed to the intrinsic high graphitization degree of GNP and the enhanced Pt-carbon interaction in Pt/GNP. If considering that GNP can be easily mass produced from graphite. GNP is a promising, low-cost, and durable electrocatalyst support for oxygen reduction in fuel cells. (C) 2010 Elsevier B.V. All rights reserved.