• 文献标题:   Fabrication of Phenanthroline Modified Graphene Nanosheets Decorated with Palladium Nanoparticles
  • 文献类型:   Article
  • 作  者:   LINGAPPAN N, KIM DH, PARK C, GAL YS, LIM KT
  • 作者关键词:   graphene, noncovalent functionalization, 1 10phenanthroline, palladium nanoparticle
  • 出版物名称:   JOURNAL OF NANOSCIENCE NANOTECHNOLOGY
  • ISSN:   1533-4880 EI 1533-4899
  • 通讯作者地址:   Pukyong Natl Univ
  • 被引频次:   0
  • DOI:   10.1166/jnn.2015.8348
  • 出版年:   2015

▎ 摘  要

Palladium nanoparticles decorated modified reduced graphene oxide (RGO) composite was synthesized by a two-step process using 1,10-Phenanthroline (PHEN) as bridging agent. Firstly, the graphene oxide (GO) was non-covalently modified with the PHEN molecules through pi-pi interaction between two components. Then, the modified GO was complexed with Pd precursor and subsequently reduced from Pd2+ to Pd-0 using NaBH4 to yield Pd dispersed modified AGO sheets. The structure and morphology of the resulting composites were characterized by FTIR, TGA, EDX, FESEM, HRTEM and XRD measurements. XPS results revealed that the reduction of Pd2+ to metallic Pd was successfully achieved, while the HRTEM and FESEM micrographs suggested that the Pd nanoparticles were well-dispersed on the functionalized graphene sheets.