▎ 摘　　要

In this joint experimental and theoretical work, we investigate collective electronic excitations (plasmons) in free-standing, single-layer graphene. The energy-and momentum-dependent electron energy-loss function was measured up to 50 eV along two independent in-plane symmetry directions (Gamma M and Gamma K) over the first Brillouin zone by momentum-resolved electron energy-loss spectroscopy in a transmission electron microscope. We compare our experimental results with corresponding time-dependent density-functional theory calculations. For finite momentum transfers, good agreement with experiments is found if crystal local-field effects are taken into account. In the limit of small and vanishing momentum transfers, we discuss differences between calculations and the experimentally obtained electron energy-loss functions of graphene due to a finite momentum resolution and out-of-plane excitations.