• 文献标题:   Graphene quantum dots-decorated ZnS nanobelts with highly efficient photocatalytic performances
  • 文献类型:   Article
  • 作  者:   HAM S, KIM Y, PARK MJ, HONG BH, JANG DJ
  • 作者关键词:  
  • 出版物名称:   RSC ADVANCES
  • ISSN:   2046-2069
  • 通讯作者地址:   Seoul Natl Univ
  • 被引频次:   22
  • DOI:   10.1039/c5ra28026e
  • 出版年:   2016

▎ 摘  要

Hybrid nanostructures combining inorganic materials and graphene have shown great potential for the environmentally friendly treatment of effluents. Herein, graphene quantum dots (GQDs)-decorated ZnS nanobelts have been synthesized via a facile hydrothermal method. The electrostatic attraction of two materials and the thermal reduction of graphene are the main driving forces to fabricate well-defined composite nanostructures. GQDs in GQD/ZnS nanocomposites have been found to exist discretely and uniformly on the surfaces of ZnS nanobelts. The photocatalytic activity of GQD/ZnS nanocomposites has been found to be highest at a GQD/ZnS mass ratio of 8 x 10(-4). The photocatalytic rate constant (0.0046 min(-1)) of GQD/ZnS nanocomposites having the optimized GQD content in the photodegradation reaction of rhodamine B has been found to be 14 times higher than that of commercially available ZnS powder. Decorated GQDs introduce an additional visible-light response and serve as electron collectors and transporters to block electron-hole recombination efficiently, enhancing the photocatalytic performances of ZnS nanobelts immensely.