• 文献标题:   Hierarchical NiCo2Se4 nanoneedles/nanosheets with N-doped 3D porous graphene architecture as free-standing anode for superior sodium ion batteries
  • 文献类型:   Article
  • 作  者:   ZHOU CC, ZHANG PL, LIU JZ, ZHOU JJ, WANG WW, LI K, WU J, LEI YC, CHEN LY
  • 作者关键词:   chemical vapor deposition, threedimensional ndoped graphene, nico2se4
  • 出版物名称:   JOURNAL OF COLLOID INTERFACE SCIENCE
  • ISSN:   0021-9797 EI 1095-7103
  • 通讯作者地址:  
  • 被引频次:   20
  • DOI:   10.1016/j.jcis.2020.12.015
  • 出版年:   2021

▎ 摘  要

In order to cope with the problem of insufficient lithium metal reserves, sodium ion batteries (SIBs) are proposed and extensively studied for the next-generation batteries. In our work, hierarchical NiCo2Se4 nanoneedles/nanosheets are deposited on the skeleton of N-doped three dimensional porous graphene (NPG) by a convenient solvothermal method and subsequent gas-phase selenization process. Compared with NiCo2Se4 powder, the optimized NiCo2Se4/N-doped porous graphene composite (denoted as NCS@NPG) as self-supporting anode exhibits the excellent electrode activity for SIBs, with a specific capacity of 500 mAh/g and 257 mAh/g at a current density of 0.2 A/g and 6.4 A/g, respectively. The high specific capacity as well as rate capacity can be attributed to the three-dimensional graphene skeleton with high electrical conductivity and pore structure, which provides convenient ion and electron transmission channels. (c) 2020 Elsevier Inc. All rights reserved.