• 文献标题:   Atomic and Polymeric Carbon on Co(0001): Surface Reconstruction, Graphene Formation, and Catalyst Poisoning
  • 文献类型:   Article
  • 作  者:   WESTSTRATE CJ, KIZILKAYA AC, ROSSEN ETR, VERHOEVEN MWGM, CIOBICA IM, SAIB AM, NIEMANTSVERDRIET JW
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF PHYSICAL CHEMISTRY C
  • ISSN:   1932-7447
  • 通讯作者地址:   Eindhoven Univ Technol
  • 被引频次:   49
  • DOI:   10.1021/jp301706q
  • 出版年:   2012

▎ 摘  要

Atomic carbon on Co(0001), deposited by ethylene decomposition, forms islands with a (root 3 x root 3)R30 degrees structure at low C coverage (similar to 0.2 ML), whereas a high C coverage (0.5 ML, saturation) induces a reconstruction of the cobalt surface. Atomic carbon weakens the adsorption of CO and H-2, but even a saturated atomic carbon layer does not block the surface for adsorption. Carbon carbon coupling, i.e., polymeric carbon formation, was not observed for temperatures