• 文献标题:   Synthesis and optimization of microwave-assisted exfoliated functionalized graphene as an efficient catalyst in biodiesel production
  • 文献类型:   Article
  • 作  者:   ROUCHI MB, KHANMOHAMMADI M, GARMARUDI AB, DE LA GUARDIA M
  • 作者关键词:   biodiesel, graphene oxide, heterogeneous catalyst, synthesi, nano structure characterization, reaction optimization
  • 出版物名称:   FULLERENES NANOTUBES CARBON NANOSTRUCTURES
  • ISSN:   1536-383X EI 1536-4046
  • 通讯作者地址:   Imam Khomeini Int Univ
  • 被引频次:   0
  • DOI:   10.1080/1536383X.2018.1493459
  • 出版年:   2018

▎ 摘  要

In this study, the capability of functionalized graphene was investigated as heterogeneous catalyst in biodiesel production from vegetable oil. Graphene oxide was fabricated from graphite via carrier improved method, and its exfoliation was carried out by microwave radiation. The exfoliated sample was reduced and sulfonated, being analyzed by Fourier transform Infrared, Scanning Microscopy Transmission Electron Microscopy, X-ray diffraction and element mapping. The catalyst was employed in biodiesel production reaction and effective reaction parameters were studied. The optimized reaction temperature, time and catalyst percentage were 178 degrees C, 3 h and 1.9% respectively. It was observed that modified graphene, due to its high surface area and presence of sulfonic acid functional groups, is a suitable catalyst with reasonable capability providing a 98% synthesis yield, also in the present study it was prepared from graphite which is a very cheap material.