• 文献标题:   Experimental study on the reducibility of graphene oxide by hydrazine hydrate
  • 文献类型:   Article
  • 作  者:   ZHU PY, SHEN M, XIAO SH, ZHANG D
  • 作者关键词:   nanostructure, graphene oxide, reduction, fourier transform infrared spectroscopy
  • 出版物名称:   PHYSICA BCONDENSED MATTER
  • ISSN:   0921-4526 EI 1873-2135
  • 通讯作者地址:   Tongji Univ
  • 被引频次:   35
  • DOI:   10.1016/j.physb.2010.11.022
  • 出版年:   2011

▎ 摘  要

In this paper, we focus on the reducibility of graphene oxide by hydrazine hydrate. The main emphasis is placed on the problem of the dosage of hydrazine hydrate and the reaction time on the reduction of chemical groups. This paper describes a system for the analysis of FT-IR. A model is developed for the FT-IR analysis using exponential decay function (Y = Y(0)e(-RX)). The height of the peaks in FT-IR spectra of the chemical groups was fitted with exponential decay function. Decay constant R is given the name of Reducibility Factor R. Emphasis is placed on the decay constant R in the fitting functions by which the reducibility of the chemical groups on graphene oxide is evaluated. It is found that R is different for different chemical groups. The sequence is R-OH > R-C=O > RC-O-C. This means that C-O-C is the most difficult one to be reduced. OH is the most easy, and C=O is between C-O-C and OH. The experimental results reveal a basis for the research of the application of graphene oxide. (C) 2010 Elsevier B.V. All rights reserved.