• 文献标题:   Hierarchical metal-organic framework derived nitrogen-doped porous carbon/graphene composite for high performance supercapacitors
  • 文献类型:   Article
  • 作  者:   XIN LJ, LIU Q, LIU JY, CHEN RR, LI RM, LI ZS, WANG J
  • 作者关键词:   metalorganic framework, high nitrogendoped porous carbon, symmetric supercapacitor
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Harbin Engn Univ
  • 被引频次:   18
  • DOI:   10.1016/j.electacta.2017.07.138
  • 出版年:   2017

▎ 摘  要

Nanocomposites of graphene and N-doped porous carbon (HPNCs/rGO-800) are prepared via facile carbonization of Zn-metal-organic frameworks (ZIF-8) by controlling appropriate temperature. In comparison with the single N-doped porous carbon (HPNCs-800) which are made from the pure ZIF-8, HPNCs/rGO-800 reduce the agglomeration of ZIF-8 and promote electrical conductivity. In this work, HPNCs/rGO-800 materials exhibit excellent electrochemical performances with a high specific capacitance of 245 F g(-1) in 6 M KOH electrolyte at a current density of 1 A g(-1). Moreover, HPNCs/rGO-800//HPNCs/rGO-800 symmetric supercapacitor reaches a superior energy density of 18.0 Wh kg(-1) at a power density of 475 W kg(-1) in the wide voltage region of 0-1.8 V, and a superb cycle stability (90% capacitance retention after 10,000 cycles). Such outstanding electrochemical behavior shows that the device is a promising practical energy-storage facility. (C) 2017 Elsevier Ltd. All rights reserved.