• 文献标题:   Formation of graphene-wrapped multi-shelled NiGa2O4 hollow spheres and graphene-wrapped yolk-shell NiFe2O4 hollow spheres derived from metal-organic frameworks for high-performance hybrid supercapacitors
  • 文献类型:   Article
  • 作  者:   MOHAMMADI ZARDKHOSHOUI A, HOSSEINY DAVARANI SS
  • 作者关键词:  
  • 出版物名称:   NANOSCALE
  • ISSN:   2040-3364 EI 2040-3372
  • 通讯作者地址:   Shahid Beheshti Univ
  • 被引频次:   16
  • DOI:   10.1039/c9nr09108d
  • 出版年:   2020

▎ 摘  要

To construct a supercapacitor (SC) with considerable performance, synthesis of an electrode material with a highly porous structure is necessary. Herein, an efficient metal-organic framework (MOF)-derived procedure is offered to construct a graphene wrapped multi-shelled NiGa2O4 hollow sphere (GW-MSNGOHS) positive electrode material and a graphene-wrapped yolk-shell NiFe2O4 hollow sphere (GW-YS-NFOHS) negative electrode material with a highly porous nature in SCs. The GW-MSNGOHS and GW-YS-NFOHS electrodes exhibit excellent capacities (similar to 411.25 mA h g(-1) and 254.25 mA h g(-1), respectively, at 1 A g(-1)), reasonable rate performances (75.85%, and 62.7%, respectively), and outstanding cyclability (98.9% and 90.9%, respectively). Benefiting from the reasonably engineered negative and positive electrodes, the fabricated asymmetric device (GW-MSNGOHS//GW-YS-NFOHS) can show an excellent energy density (ED) of 118.97 W h kg(-1) at a power density (PD) of 1702 W kg(-1), an exceptional robustness of 92.1%, and an excellent capacity (C-s) of 140.2 mA g(-1).