• 文献标题:   "Turn on" fluorescence enhancement of Zn octacarboxyphthaloyanine-graphene oxide conjugates by hydrogen peroxide
  • 文献类型:   Article
  • 作  者:   SHUMBA M, MASHAZI P, NYOKONG T
  • 作者关键词:   reduced graphene oxide nanosheet, zinc octacarboxyphthalocyanine, photoinduced electron transfer, fluorescence enhancement
  • 出版物名称:   JOURNAL OF LUMINESCENCE
  • ISSN:   0022-2313 EI 1872-7883
  • 通讯作者地址:   Rhodes Univ
  • 被引频次:   3
  • DOI:   10.1016/j.jlumin.2015.11.001
  • 出版年:   2016

▎ 摘  要

Zn octacarboxy phthalocyanine-reduced graphene oxide or graphene oxide conjugates were characterized by absorption spectroscopy, transmission electron microscopy, fluorescence spectroscopy, X-ray diffraction, thermo gravimetric analysis and X-ray photon spectroscopy. The presence of reduced graphene oxide or graphene oxide resulted in the quenching (turn on) of Zn octacarboxy phthalocyanine fluorescence which can be explained by photoinduced electron transfer. Zn octacarboxy phthalocyanine-reduced graphene oxide or graphene oxide conjugates "turned on" fluorescence showed a linear response to hydrogen peroxide hence their potential to be used as sensors. The nanoprobe developed showed high selectivity towards hydrogen peroxide in the presence of physiological interferences. (C) 2015 Elsevier B.V. All rights reserved.