• 文献标题:   One-pot low-temperature green synthesis of magnetic graphene nanocomposite for the selective reduction of nitrobenzene
  • 文献类型:   Article
  • 作  者:   HARIDAS V, SUGUNAN S, NARAYANAN BN
  • 作者关键词:   graphene, mild sonication, magnetic graphene catalyst, nitrobenzene reduction
  • 出版物名称:   JOURNAL OF SOLID STATE CHEMISTRY
  • ISSN:   0022-4596 EI 1095-726X
  • 通讯作者地址:   Univ Calicut
  • 被引频次:   0
  • DOI:   10.1016/j.jssc.2018.03.037
  • 出版年:   2018

▎ 摘  要

In the present study, a green one-pot low-temperature method is adopted for the synthesis of a novel magnetic graphene nanocomposite catalyst. Graphene preparation is performed without employing any oxidizing agents or corrosive chemicals, under mild sonication in isopropyl alcohol - water mixture. Monolayered nanoplatelets of graphene are obtained in the green solvent mixture and the composite material is found to be ferromagnetic in nature, obvious from the vibrating sample magnetometric measurements. Fe in the nanocomposite exists in two different forms i.e., alpha-Fe2O3 and alpha-FeOOH, as evident from the material characterization results. The graphene nanocomposite is found to be highly efficient in the selective reduction of nitrobenzene to aniline under solvent free reaction conditions and magnetic separation of this fine nanomaterial from the reaction mixture is successfully carried out. The catalyst is efficiently reusable till five repeated cycles.