• 文献标题:   Reduced Graphene Oxide-Doped Poly(N-alkyl-3,4-dihydrothieno[3,4-b][1,4]oxazine) with High Sensitivity of Indole-3-Acetic Acid
  • 文献类型:   Article
  • 作  者:   QU K, MING SL, JIA HY, GUO B, LIU XM, JIAN NN, NIU GF, LU BY, XU JK
  • 作者关键词:   poly nmethyl3 4dihydrothieno3 4b1 4oxazine, sensor, indole3acetic acid, graphene oxide
  • 出版物名称:   INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE
  • ISSN:   1452-3981
  • 通讯作者地址:   Jiangxi Sci Technol Normal Univ
  • 被引频次:   0
  • DOI:   10.20964/2018.12.12
  • 出版年:   2018

▎ 摘  要

A highly sensitive electrochemical sensor for detecting indole-3-acetic acid (IAA) was constructed based on the composite of poly(N-methyl-3,4-dihydrothieno[3,4-b][1,4]oxazine) (PMDTO) and reduced graphene oxide (RGO) (PMDTO/RGO). The PMDTO/RGO modified electrode was prepared by electrochemical polymerization of MDTO followed by the electrochemical reduction GO in their homogeneous aqueous solution. SEM demonstrated that PMDTO was covered with plate-like graphene through the two-step electrodeposition. The RGO, featuring large surface area and excellent conductivity, could not only improve the conductivity of the sensor, but also load more PMDTO to amplify the signal. The fabricated electrochemical sensor showed a low detection limit of 3x10(-8) M and a wide linear range from 0.1 to 10 mu M for the recognition of IAA.