• 文献标题:   Synthesis of "L-cysteine-graphene oxide" hybrid by new methods and elucidation of its uptake properties for Hg(II) ion
  • 文献类型:   Article
  • 作  者:   DANESHMAND M, OUTOKESH M, AKBARI A, KOSARI M, TAYYEBI A
  • 作者关键词:   graphene oxide, lcysteine, mercury hg, adsorption capacity, nucleophilic covalent adsorbent
  • 出版物名称:   SEPARATION SCIENCE TECHNOLOGY
  • ISSN:   0149-6395 EI 1520-5754
  • 通讯作者地址:   Sharif Univ Technol
  • 被引频次:   2
  • DOI:   10.1080/01496395.2017.1418889
  • 出版年:   2018

▎ 摘  要

This study introduces two new, simple, and scalable methods for synthesis of cysteine-graphene oxide hybrid, namely nucleophilic and covalent methods. Produced adsorbents could uptake 500 and 600mg Hg2+/g, respectively, which are larger than capacities of most of the commercial adsorbents. By means of different instrumental techniques, chemical structures of the obtained graphene products were disclosed, and two pertinent mechanisms for their formations were suggested. Time for attaining uptake equilibrium for nucleophilic/covalent samples was 30min/150min, and kinetics was controlled by liquid film resistance/chemical reaction mechanisms, respectively. High selectivity and good regenerability are other key features of the prepared adsorbents.