• 文献标题:   Porous CuO/reduced graphene oxide composites synthesized from metal-organic frameworks as anodes for high-performance sodium-ion batteries
  • 文献类型:   Article
  • 作  者:   LI DS, YAN D, ZHANG XJ, LI JB, LU T, PAN LK
  • 作者关键词:   sodiumion batterie, anode material, cuo/rgo, microwaveassisted method, metalorganic framework
  • 出版物名称:   JOURNAL OF COLLOID INTERFACE SCIENCE
  • ISSN:   0021-9797 EI 1095-7103
  • 通讯作者地址:   East China Normal Univ
  • 被引频次:   23
  • DOI:   10.1016/j.jcis.2017.03.037
  • 出版年:   2017

▎ 摘  要

Currently, metal-organic frameworks (MOFs) and their derivates have attracted great interest as a new kind of electrode material for energy storage devices, mainly due to their designable framework structures, abundant pore structures, adjustable pore and particle sizes. In this work, porous CuO/reduced graphene oxide (RGO) composites were obtained through the pyrolysis of Cu-based MOFs/graphene oxide under microwave irradiation, and investigated as anode materials for sodium-ion batteries (SIBs). CuO/RGO composites exhibit a maximum specific capacity of 466.6 mA h g(-1) after 50 galvanostatic charge/discharge cycles at a current density of 100 mA g(-1). Even at a high current density of 2 A g(-1), a capacity of 347.6 mA h g(-1) is still maintained with stable cycling. The superior electrochemical performance, which is better than those of CuO-based electrodes reported previously, makes the CuO/RGO composites to be applied promisingly as anodes for high-performance SIBs. (C) 2017 Elsevier Inc. All rights reserved.