• 文献标题:   Radiation grafting graphene oxide reinforced polybenzimidazole membrane with a sandwich structure for high temperature proton exchange membrane fuel cells in anhydrous atmosphere
  • 文献类型:   Article
  • 作  者:   CAI YB, YUE ZY, TENG X, XU SA
  • 作者关键词:   threelayer membrane, proton exchange membrane, polybenzimidazole, radiation grafting graphene oxide, phosphoric acid doping
  • 出版物名称:   EUROPEAN POLYMER JOURNAL
  • ISSN:   0014-3057 EI 1873-1945
  • 通讯作者地址:   East China Univ Sci Technol
  • 被引频次:   2
  • DOI:   10.1016/j.eurpolymj.2018.02.020
  • 出版年:   2018

▎ 摘  要

A three-layer membrane (TLM) of radiation grafting graphene oxide reinforced polybenzimidazole/porous polybenzimidazole/radiation grafting graphene oxide reinforced polybenzimidazole (PBI-RGO/PPBI/PBI-RGO) was fabricated and then doped with phosphoric acid (PA) for high temperature proton exchange membranes (HT-PEMs) in anhydrous atmosphere. These TLMs have a sandwich structure and the diameter of most pores falls in the range between 500 nm and 2 mu m. PA doped TLMs display excellent mechanical strength and oxidative stability. The tensile strength of PA doped PBI-RGO/PPBI/PBI-RGO membranes ranges from 22.7 to 38.5 MPa, which is significantly higher than that of PA doped PPBI membrane (7.9 MPa). The introduction of RGO and porous structure can improve the proton conductivity of membranes. The proton conductivity of PA doped PBI-RGO/PPBI-80/PBI-RGO membrane is 113.8 mS. cm(-1) at 170 degrees C without humidity, with an increase of 4.9 times compared with that of PA doped PBI membrane. The sandwich structure endows the membrane with lower PA leakage and higher proton conductivity, thus making it a promising membrane for HT-PEM applications.