• 文献标题:   Highly sensitive electrochemical determination of Sunset Yellow based on gold nanoparticles/graphene electrode
  • 文献类型:   Article
  • 作  者:   WANG J, YANG BB, WANG HW, YANG P, DU YK
  • 作者关键词:   graphene, au nanoparticle, sunset yellow, electrochemical determination
  • 出版物名称:   ANALYTICA CHIMICA ACTA
  • ISSN:   0003-2670 EI 1873-4324
  • 通讯作者地址:   Soochow Univ
  • 被引频次:   35
  • DOI:   10.1016/j.aca.2015.08.042
  • 出版年:   2015

▎ 摘  要

An electrochemical sensor was prepared using Au nanoparticles and reduced graphene successfully decorated on the glassy carbon electrode (Au/RGO/GCE) through an electrochemical method which was applied to detect Sunset Yellow (SY). The as-prepared electrode was characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), atomic force microscopy (AFM) and electrochemical measurements. The results of cyclic voltammetry (CV) proved that Au/RGO/GCE had the highest catalytic activity for the oxidation of SY as compared with GCE, Au/GCE, and RGO/GCE. Differential pulse voltammetry (DPV) showed that the linear calibration curves for SY on Au/RGO/GCE in the range of 0.002 mu M-109.14 mu M, and the detection limit was estimated to be 2 nM (S/N = 3). These results suggested that the obtained Au/RGO/GCE was applied to detect SY with high sensitivity, low detection limit and good stability, which provided a promising future for the development of portable sensor in food additives. (C)2015 Elsevier B.V. All rights reserved.