• 文献标题:   Transition of graphene oxide-coated fiber bundles from insulator to conductor by chemical reduction
  • 文献类型:   Article
  • 作  者:   HA DH, JUNG S, KIM HJ, KIM D, KIM WJ, YI SN, JUN Y, YUN YJ
  • 作者关键词:   graphene oxide, polymer, chemical reduction, raman spectroscopy, electrical conductance
  • 出版物名称:   SYNTHETIC METALS
  • ISSN:   0379-6779
  • 通讯作者地址:   Korea Res Inst Stand Sci
  • 被引频次:   15
  • DOI:   10.1016/j.synthmet.2015.03.018
  • 出版年:   2015

▎ 摘  要

We fabricate graphene oxide (GO)-coated fiber bundles via electrostatic deposition of GO sheets on polyester/cotton fiber bundles and investigate the changes in their properties by chemical reduction in a hydroiodic acid solution. The structural properties of GO sheets change rapidly upon exposure to reduction agents but remain under a high defect density regime after the reduction. The electrical resistance of the fiber bundles decreases logarithmically for the first minute of the reduction. In contrast to the structural property, a longer chemical reduction over tens of minutes deteriorates the electrical property. The effect of chemical reduction on the electrical conductance of GO-coated fiber bundles is discussed based on the competition of various factors, such as the number of conducting pathways and the carrier density, among others. (C) 2015 Elsevier B.V. All rights reserved.