• 文献标题:   Synthesis of disperse graphene-like materials and their structural and electrochemical characteristics
  • 文献类型:   Article
  • 作  者:   MALEEVA EA, TARASEVICH MR
  • 作者关键词:   graphite, graphenelike material, reduction, structural characteristic
  • 出版物名称:   RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A
  • ISSN:   0036-0244 EI 1531-863X
  • 通讯作者地址:   Russian Acad Sci
  • 被引频次:   1
  • DOI:   10.1134/S0036024414080160
  • 出版年:   2014

▎ 摘  要

Graphene-like materials of oxidized graphite (OG) were obtained by boiling in ethylene glycol, microwave treatment of a suspension of OG in ethylene glycol, and microwave treatment of dry OG without using solvents. The obtained materials were characterized by X-ray photoelectron spectroscopy (XPS), IR spectroscopy, atomic force microscopy, elemental analysis, and electrochemical measurements. Microwave treatment of dry OG gave the most disperse material (similar to 400 m(2)/g) with an oxygen content of no more than 20%. Treatment in 0.5 M H2SO4 for 50 h at 60A degrees C in oxygen did not lead to oxidation and was accompanied by an increase in the dispersity of this material.