• 文献标题:   Ionic liquid-stabilized graphene and its use in immobilizing a metal nanocatalyst
  • 文献类型:   Article
  • 作  者:   XIAO WJ, SUN ZY, CHEN S, ZHANG HY, ZHAO YF, HUANG CL, LIU ZM
  • 作者关键词:  
  • 出版物名称:   RSC ADVANCES
  • ISSN:   2046-2069
  • 通讯作者地址:   Chinese Acad Sci
  • 被引频次:   23
  • DOI:   10.1039/c2ra20774e
  • 出版年:   2012

▎ 摘  要

A new ionic liquid (IL), 1-butyl-3-methylimidazolium cholate, was first synthesized through an ion exchange reaction of 1-butyl-3-methylimidazolium chloride with sodium cholate. Stable aqueous dispersions of graphene were achieved by exfoliating graphite in the presence of the IL under ultrasonication. Both transmission electron microscopy and Raman measurements showed that the IL-stabilized graphene (IL-G) sheets existed with only a few (<5) layers. Furthermore, the IL-G was used to immobilize noble metal nanoparticles (Pt, Pd, Ru, Rh, etc), and a series of graphene-metal (G-M) composites with metal size