• 文献标题:   Decorating graphene oxide with CuO nanoparticles in a water-isopropanol system
  • 文献类型:   Article
  • 作  者:   ZHU JW, ZENG GY, NIE FD, XU XM, CHEN S, HAN QF, WANG X
  • 作者关键词:  
  • 出版物名称:   NANOSCALE
  • ISSN:   2040-3364
  • 通讯作者地址:   Nanjing Univ Sci Technol
  • 被引频次:   118
  • DOI:   10.1039/b9nr00414a
  • 出版年:   2010

▎ 摘  要

A facile chemical procedure capable of aligning CuO nanoparticles on graphene oxide (GO) in a water-isopropanol system has been described. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) observations indicate that the exfoliated GO sheets are decorated randomly by spindly or spherical CuO nanoparticle aggregates, forming well-ordered CuO: GO nanocomposites. A formation mechanism of these interesting nanocomposites is proposed as intercalation and adsorption of Cu2+ ions onto the GO sheets, followed by the nucleation and growth of the CuO crystallites, which in return resulted in the exfoliation of GO sheets. Moreover, the obtained nanocomposites exhibit a high catalytic activity for the thermal decomposition of ammonium perchlorate (AP), due to the concerted effect of CuO and GO.