• 文献标题:   Graphene-Like MoS2/Graphene Composites: Cationic Surfactant-Assisted Hydrothermal Synthesis and Electrochemical Reversible Storage of Lithium
  • 文献类型:   Article
  • 作  者:   HUANG GC, CHEN T, CHEN WX, WANG Z, CHANG K, MA L, HUANG FH, CHEN DY, LEE JY
  • 作者关键词:   molybdenum disulfide, graphene, composite, hydrothermal synthesi, lithium ion storage
  • 出版物名称:   SMALL
  • ISSN:   1613-6810 EI 1613-6829
  • 通讯作者地址:   Zhejiang Univ
  • 被引频次:   231
  • DOI:   10.1002/smll.201300415
  • 出版年:   2013

▎ 摘  要

A cationic surfactant-assisted hydrothermal route is developed for the facile synthesis of graphene-like MoS2/graphene (GL-MoS2/G) composites based on the hydrothermal reduction of Na2MoO4 and graphene oxide sheets with L-cysteine in the presence of cetyltrimethylammonium bromide (CTAB), following by annealling in N-2 atmosphere. The GL-MoS2/G composites are characterized by X-ray diffraction, electron microscopy, high-resolution transmission electron microscopy, and Raman spectroscopy. The effects of CTAB concentration on the microstructures and electrochemical performances of the composites for reversible Li+ storage are investigated. It is found that the layer number of MoS2 sheets decreases with increasing CTAB concentration. The GL-MoS2 sheets in the composites are few-layer in the case of 0.01 approximate to 0.03 mol L-1 CTAB of hydrothermal solution and single-layer in the case of 0.05 mol L-1 CTAB. The GL-MoS2/G composites prepared with 0.01-0.02 molL(-1) of CTAB solution exhibit a higher reversible capacity of 940-1020 mAh g(-1), a greater cycle stability, and a higher rate capability than other samples. The exceptional electrochemical performance of GL-MoS2/G composites for reversible Li+ storage could be attributed to an effective integration of GL-MoS2 sheets and graphene that maximizes the synergistic interaction between them.