• 文献标题:   Fabrication of exfoliated graphene-based polypropylene nanocomposites with enhanced mechanical and thermal properties
  • 文献类型:   Article
  • 作  者:   SONG PG, CAO ZH, CAI YZ, ZHAO LP, FANG ZP, FU SY
  • 作者关键词:   graphene, polypropylene, mechanical properties thermal propertie
  • 出版物名称:   POLYMER
  • ISSN:   0032-3861 EI 1873-2291
  • 通讯作者地址:   Zhejiang Univ
  • 被引频次:   344
  • DOI:   10.1016/j.polymer.2011.06.045
  • 出版年:   2011

▎ 摘  要

Despite the great potential of graphene as the nanofiller, to achieve homogeneous dispersion remains the key challenge for effectively reinforcing the polymer. Here, we report an eco-friendly strategy for fabricating the polymer nanocomposites with well-dispersed graphene sheets in the polymer matrix via first coating graphene using polypropylene (PP) latex and then melt-blending the coated graphene with PP matrix. A similar to 75% increase in yield strength and a similar to 74% increase in the Young's modulus of PP are achieved by addition of only 0.42 vol% of graphene due to the effective external load transfer. The glass transition temperature of PP is enhanced by similar to 2.5 degrees C by incorporating only 0.041 vol% graphene. The thermal oxidative stability of PP is also remarkably improved with the addition of graphene, for example, compared with neat PP, the initial degradation temperature is enhanced by 26 degrees C at only 0.42 vol% of graphene loading. (C) 2011 Elsevier Ltd. All rights reserved.