• 文献标题:   Electrochemical manufacture of graphene oxide/polyaniline conductive membrane for antibacterial application and electrically enhanced water permeability
  • 文献类型:   Article
  • 作  者:   LI BJ, TANG WJ, SUN D, LI BB, GE YX, YE X, FANG W
  • 作者关键词:   graphene oxide, polyaniline membrane, electrochemical preparation, water permeability, antibacterial
  • 出版物名称:   JOURNAL OF MEMBRANE SCIENCE
  • ISSN:   0376-7388 EI 1873-3123
  • 通讯作者地址:  
  • 被引频次:   8
  • DOI:   10.1016/j.memsci.2021.119844 EA SEP 2021
  • 出版年:   2021

▎ 摘  要

Electrofiltration, an effective approach for membrane fouling mitigation, is significantly limited by membrane properties. A facile electrochemical method was proposed to fabricate the graphene oxide/sulfuric acid-doped polyaniline (GO/S-PANI) membrane. For which, charging the graphite in H2SO4 (98 wt%) to obtain graphite intercalation compound (GIC), then in a mixed electrolyte (H2SO4, CuSO4, (NH4)(2)SO4), GO was exfoliated and assembled concurrently on the PANI membrane, which was doped by H2SO4 simultaneously. The introduction of Cu2+ made the GO layers on the membrane stable. Also, the GO/S-PANI membrane showed higher conductivity (55.6 S m(-1)) than the PANI membrane (0.019 S m(-1)). Moreover, GO/S-PANI membrane possessed a more applicable pore structure and improved hydrophilicity. As a result, membrane rejection increased, and the resistance to the negatively charged pollutants was enhanced. For 1 V electrofiltration of yeast suspension, water permeation was sustainably raised by using GO/S-PANI membrane than PANI membrane. The GO/S-PANI membrane was more stable with 1 V than without electric fields. The antibacterial rate can reach 92.1% for the GO/S-PANI membrane against Escherichia coli. Overall, our strategy provides a facile preparation method for the GO/S-PANI conductive membrane with application potential in electrofiltration and antibacterial fields.