• 文献标题:   Sensitive electrochemical detection of endocrine disruptor bisphenol A (BPA) in milk based on iodine-doped graphene
  • 文献类型:   Article
  • 作  者:   WANG KP, HU JM, ZHANG X
  • 作者关键词:   electrochemical sensor, endocrine disruptor bisphenol a, iodinedoped graphene, milk sample
  • 出版物名称:   MICROCHEMICAL JOURNAL
  • ISSN:   0026-265X EI 1095-9149
  • 通讯作者地址:  
  • 被引频次:   10
  • DOI:   10.1016/j.microc.2021.107047 EA DEC 2021
  • 出版年:   2022

▎ 摘  要

A novel electrochemical sensor for bisphenol A (BPA) detection was constructed on a glassy carbon electrode (GCE) coated with iodine-doped graphene (I-RGO). The I-RGO material was facilely prepared by simultaneous iodine-doping and reduction of graphene oxide (GO) with hydrogen iodide solution. The electrochemical performance of developed electrode was examined using electrochemical impedance spectra (EIS), cyclic voltammetry (CV) and differential pulse voltammetry (DPV) techniques. Under the optimal experimental conditions, the sensor presented a good linear response between the current and the BPA concentration range of 0.04-4.5 mu M, with a low detection limit of 0.02 mu M (S/N = 3). The developed I-RGO/GCE sensor has high selectivity, good stability and excellent reproducibility. Moreover, it has been successfully applied for BPA detection in real milk samples with satisfying recovery results.