• 文献标题:   One-pot synthesis and electrochemical properties of nitrogen-doped graphene decorated with M(OH)(x) (M = FeO, Ni, Co) nanoparticles
  • 文献类型:   Article
  • 作  者:   XIA XF, LEI W, HAO QL, WANG WJ, SUN YX, WANG X
  • 作者关键词:   doped graphene, supercapacitor, electrode material, metal hydroxide, metal oxidehydroxide, electrochemical property
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Nanjing Univ Sci Technol
  • 被引频次:   38
  • DOI:   10.1016/j.electacta.2013.09.072
  • 出版年:   2013

▎ 摘  要

To improve the electrochemical properties of chemically synthesized graphene hybrids, nitrogen-doped (N-doped) graphene decorated with M(OH)(x) (M =FeO, Ni, Co) nanoparticles were fabricated by a one-pot method at a mild temperature (95 degrees C). Urea plays an important role in the synthesis process; it not only acts as the reducing agent and doping agent for N-doped graphene, but also as a hydroxyl donor for the fabrication of metal hydroxides and oxide-hydroxide. With the help of N-doped graphene and urea, FeOOH nanorods, Co(OH)(2) nanowires and flower-like Ni(OH)(2) nanoparticles were grown on the graphene sheets. The N-doped graphene hybrids exhibited the significantly improved electrochemical performances compared to the undoped equivalents or the separate components. (C) 2013 Elsevier Ltd. All rights reserved.