• 文献标题:   Coal derived graphene as an efficient supercapacitor electrode material
  • 文献类型:   Article
  • 作  者:   SINGH A, OJHA AK
  • 作者关键词:   coal, graphene, electrode material, supercapacitor
  • 出版物名称:   CHEMICAL PHYSICS
  • ISSN:   0301-0104 EI 1873-4421
  • 通讯作者地址:   Motilal Nehru Natl Inst Technol Allahabad
  • 被引频次:   3
  • DOI:   10.1016/j.chemphys.2019.110607
  • 出版年:   2020

▎ 摘  要

We report simple and cost effective production of water soluble graphene sheets using coal. The synthesized coal derived graphene (CDG) sheets were characterized by X-ray diffraction (XRD), high-resolution transmission electron microscopy (HRTEM), field emission scanning electron microscopy (FESEM), Raman, Fourier transform infrared (FTIR), ultra-violet visible (UV-vis) spectroscopy, and photoluminescence (PL) measurements. The presence of edge oxygen functionalities in CDG sheets causes to induce fluorescent properties. The nature emission peak does not change with varying the excitation wavelength. To determine its energy storage properties, cyclic voltammetry (CV), charge-discharge and electrochemical impedance spectroscopy (EIS) measurements were done in different electrolytes. The value of specific capacitance (SC) of CDG in 1 M Na2SO4 electrolyte turns out to be 277 F/g at scan rate of 5 mV/s. CDG show long cycle stability i.e., the value of SC remains at similar to 91% after 2000 cycles at the current density of 10 mA/g.