▎ 摘　　要

A N,O-codoped hierarchical porous nanocomposite consisting of binary reduced graphene oxide and pyrolytic carbon (rGO/PC) from chitosan is fabricated. The optimized rGO/PC possesses micropores with size distribution concentrated around 1.1 nm and plenty of meso/macropores. The Brunauer-Emmett-Teller specific surface area is 480.8 m(2) g(-1), and it possesses impressively large pore volume of 2.14 cm(3) g(-1). On the basis of the synergistic effects of the following main factors: (i) the confined space effect in the hierarchical porous binary carbonaceous matrix; (ii) the anchor effects by strong chemical bonds with codoped N and O atoms; and (iii) the good flexibility and conductivity of rGO, the rGO/PC/S holding 75 wt % S exhibits high performance as Li-S battery cathode. Specific capacity of 1625 mA h g(-1) can be delivered at 0.1 C (1 C = 1675 mA g-1), whereas 848 mA h g(-1) can be maintained after 300 cycles at 1 C. Even at high rate of 5 C, 412 mA h g(-1) can be restrained after 1000 cycles.