• 文献标题:   Graphene oxide as a metal-free catalyst for oxidation of primary amines to nitriles by hypochlorite
  • 文献类型:   Article
  • 作  者:   PRIMO A, PUCHE M, PAVEL OD, COJOCARU B, TIRSOAGA A, PARVULESCU V, GARCIA H
  • 作者关键词:  
  • 出版物名称:   CHEMICAL COMMUNICATIONS
  • ISSN:   1359-7345 EI 1364-548X
  • 通讯作者地址:   Univ Politecn Valencia
  • 被引频次:   26
  • DOI:   10.1039/c5cc09463a
  • 出版年:   2016

▎ 摘  要

Graphene oxide catalyzes oxidation by NaClO of primary benzyl and aliphatic amines to a product distribution comprising nitriles and imines. Nitriles are the sole product for long chain aliphatic amines. Spectroscopic characterization suggests that percarboxylic and perlactone groups could be the active sites of the process.