▎ 摘　　要

High-capacity anode materials for lithium ion batteries (LIBs), such as spinel-type metal oxides, generally suffer from poor Li+ and e(-) conductivities. Their drastic crystal structure and volume changes, as a result of the conversion reaction mechanism with Li, severely impede the high-rate and cyclability performance toward their practical application. In this article, we present a general and facile approach to fabricate flexible spinet-type oxide/reduced graphene oxide (rGO) composite aerogels as binder-free anodes where the spinet nanoparticles (NPs) are integrated in an interconnected rGO network. Benefiting from the hierarchical porosity, conductive network and mechanical stability constructed by interpenetrated rGO layers, and from the pillar effect of NPs in between rGO sheets, the hybrid system synergistically enhances the intrinsic properties of each component, yet is robust and flexible. Consequently, the spinel/rGO composite aerogels demonstrate greatly enhanced rate capability and long-term stability without obvious capacity fading for 1000 cycles at high rates of up to 4.5 A g(-1) in the case of CoFe2O4. This electrode design can successfully be applied to several other spinet ferrites such as MnFe2O4, Fe3O4, NiFe2O4 or Co3O4, all of which lead to excellent electrochemical performances.