• 文献标题:   Hydrothermal synthesis and pseudo capacitance behavior of a highly homogeneous dispersed graphene sheets/ruthenium oxide nanocomposite
  • 文献类型:   Article
  • 作  者:   LENG X, ZOU JP, XIONG X, HE HW
  • 作者关键词:  
  • 出版物名称:   RSC ADVANCES
  • ISSN:   2046-2069
  • 通讯作者地址:   Cent S Univ
  • 被引频次:   9
  • DOI:   10.1039/c4ra10321a
  • 出版年:   2014

▎ 摘  要

Nanocomposites of reduced graphene oxide (RGO) sheets decorated with amorphous ruthenium oxide nanoparticles are fabricated through a one-pot hydrothermal process without additional dispersants. During the hydrothermal reduction, unilamellar graphene sheets with curved and veil-like morphology are formed and multilamellar graphene sheets are further separated by amorphous RuO2 center dot xH(2)O with a particle size of 3-8 nm. The nanocomposites exhibit evident pseudo capacitance behavior and the comprehensive electrochemical performance is improved markedly compared with that of the single components. When the precursor ratio of graphene oxide (GO) to RuCl3 center dot xH(2)O is 2 : 10, the graphene-RuO2 (GR) nanocomposite electrode achieves the highest specific capacitance of 542.5 F g(-1) and the minimum ESR value of 1.21 Omega at 0.1 A g(-1), retaining 94% after 1000 cycles at 1 A g(-1). Thus graphene sheets/ruthenium oxide nanocomposites bode well for a promising candidate in supercapacitor technology.