• 文献标题:   Binder-free and self-supported reduced graphene oxide coated Cu2SnS3/Carbon nanofibers for superior lithium storage
  • 文献类型:   Article
  • 作  者:   CHEN X, LIN J, CHEN YL, ZHANG J, JIANG H, QIU FY, CHU RX, GUO H
  • 作者关键词:   copper tin sulfide, selfsupported, carbon nanofiber, reduced graphene oxide, lithiumion batterie
  • 出版物名称:   JOURNAL OF ALLOYS COMPOUNDS
  • ISSN:   0925-8388 EI 1873-4669
  • 通讯作者地址:   Xiamen Univ
  • 被引频次:   0
  • DOI:   10.1016/j.jallcom.2020.155619
  • 出版年:   2020

▎ 摘  要

To utilize the nanomaterials that could be mass manufactured for energy storage, a self-supported reduced graphene oxide (rGO) coated Cu2SnS3 (CTS)/carbon nanofiber (CNF) electrode is fabricated by the facile gelation-solvothermal-electrodeposition method, and applied in lithium-ion batteries without a binder or conductive agent. Compared with the CTS microtubes synthesized from their complex template, the CTS nanoparticles in the rGO@CTS/CNF film are anchored on the CNF surface and surrounded by the conformal rGO with varying spacings. The whole self-supported rGO@CTS/CNF electrode (including the CNF and rGO) delivers an initial capacity of 678.8 mAh g(-1) at 0.5 A g(-1), and retains at 464.2 mAh g(-1) after 200 cycles, which is superior to those of the pristine CTS microtubes and the uncoated CTS/CNF electrodes. (C) 2020 Elsevier B.V. All rights reserved.