• 文献标题:   Porous graphene sandwich/poly(vinylidene fluoride) composites with high dielectric properties
  • 文献类型:   Article
  • 作  者:   CHU LY, XUE QZ, SUN J, XIA FJ, XING W, XIA D, DONG MD
  • 作者关键词:   functional composite, sandwich, polymer, polymermatrix composite, electrical propertie
  • 出版物名称:   COMPOSITES SCIENCE TECHNOLOGY
  • ISSN:   0266-3538 EI 1879-1050
  • 通讯作者地址:   China Univ Petr
  • 被引频次:   54
  • DOI:   10.1016/j.compscitech.2013.07.001
  • 出版年:   2013

▎ 摘  要

A novel sandwich structure based on few-layer graphene nanosheets (FLGs) composed of functionalized porous graphene, pristine graphene and functionalized porous graphene is proposed. After one-step alkaline-mediated hydrothermal treatment, the outmost layers of FLGs are etched to porous structure. Sandwich FLGs/poly(vinylidene fluoride) (PVDF) composites are fabricated and the composites show excellent dielectric properties among carbon-based fillers/PVDF composites. Owing to the unique semiconductor/conductor/semiconductor structure, theoretical analysis indicates that the dielectric constant of the sandwich FLGs/PVDF composites can be as high as 10(5). Our findings provide a novel strategy to fabricate high dielectric performance graphene based composites and the process is simple, low-cost and environmentally friendly. (c) 2013 Elsevier Ltd. All rights reserved.