• 文献标题:   Modification of ZSM-5 zeolite nanoparticles by graphene oxide to improve anticorrosion properties of polyurethane coating
  • 文献类型:   Article
  • 作  者:   DARABINAJAND B, MIRMOHSENI A, NIAEI A
  • 作者关键词:   anticorrosion, calcination, electrochemical impedance spectroscopy, graphene oxide, polyurethane, zeolite
  • 出版物名称:   JOURNAL OF APPLIED POLYMER SCIENCE
  • ISSN:   0021-8995 EI 1097-4628
  • 通讯作者地址:  
  • 被引频次:   1
  • DOI:   10.1002/app.53908 EA APR 2023
  • 出版年:   2023

▎ 摘  要

Polyurethane coatings are a good option for the protection of various structures due to their unique properties. In order to improve their barrier performance against corrosive species, various nanoparticles have been embedded into polymer coating. In this project, the ZSM-5 zeolite nanoparticles are modified with graphene oxide. Field emission scanning electron microscopy and Fourier transform infrared spectroscopy are used for characterizing unmodified and GO-modified ZSM-5 zeolites. The effect of ZSM-5 zeolite and ZSM-5 zeolite modified with GO addition on the anticorrosion properties of polyurethane (PU) coating is evaluated by electrochemical impedance spectroscopy, Tafel polarization, and Pull-off tests. Modification of ZSM-5 zeolite with GO has greatly influenced the anticorrosion properties of zeolite nanoparticles in polyurethane coatings. Among various PU coatings, the PU/ZSM-5-GO coating on mild steel shows the best protective properties (highest R-ct and lowest i(corr)) against active corrosive species.