• 文献标题:   Molecular-Scale Functionality on Graphene To Unlock the Energy Capabilities of Metal Hydrides for High-Capacity Lithium-Ion Batteries
  • 文献类型:   Article
  • 作  者:   XIA GL, ZHANG BP, CHEN XW, SUN DL, GUO ZP, LIANG FX, ZOU WD, YANG ZZ, YU XB
  • 作者关键词:   lithiumion batterie, metal hydride, magnesium hydride, graphene, selfassembly
  • 出版物名称:   ACS NANO
  • ISSN:   1936-0851 EI 1936-086X
  • 通讯作者地址:   Fudan Univ
  • 被引频次:   2
  • DOI:   10.1021/acsnano.8b03280
  • 出版年:   2018

▎ 摘  要

Metal hydrides have attracted great intentions as anodes for lithium-ion batteries (LIBs) due to their extraordinary theoretical capacity. It is an unsolved challenge, however, to achieve high capacity with stable cyclability, owing to their insulating property and large volume expansion upon lithium storage. Here, we introduce self-initiated polymerization to realize molecular-scale functionality of metal hydrides with conductive polymer, that is, polythiophene (PTh), on graphene, leading to the formation of MgH2@PTh core-shell nanoparticles on graphene. The nanoscale characteristics of MgH2 not only relieve the induced stress upon volume changes but also allow fast diffusivity and high reactivity for Li-ion transport. More importantly, the conformal coating of ultrathin PTh membrane can effectively suppress the detrimental reactions between MgH2 and electrolyte, provide enhanced performance with facile electron and Li+ transport, and preserve its structural integrity, attributed to the strong molecular interaction between PTh and MgH2 as well as its various products during electrochemical reactions. With this structure, a high reversible specific capacity of 1311 mAh g(-1) at 100 mA g(-1), excellent rate performance of 1025 mAh g(-1) at 2000 mA g(-1) and a capacity retention of 84.5% at 2000 mA g(-1) after 500 cycles are observed for MgH2@PTh nanoparticles as anode for LIBs.