• 文献标题:   Graphene-Based Film Reduced by a Chemical and Thermal Synergy Method as a Transparent Conductive Electrode
  • 文献类型:   Article
  • 作  者:   MIAO JL, LIU HH, LI CB, ZHANG XX
  • 作者关键词:   graphene, mechanism, synergy reduction, transparent conductive electrode, optoelectronic
  • 出版物名称:   SCIENCE OF ADVANCED MATERIALS
  • ISSN:   1947-2935 EI 1947-2943
  • 通讯作者地址:   Tianjin Polytech Univ
  • 被引频次:   5
  • DOI:   10.1166/sam.2016.2703
  • 出版年:   2016

▎ 摘  要

Solution-processed graphene oxide (GO) films have tremendous potential in the applications of transparent electrodes. The mechanism of how the GO film is reduced by reducing gas has not been clarified because the reducing gas cannot permeate through the plane of GO. Here, an effective chemical and thermal synergy reduction of GO film was investigated. We also revealed how the reducing gas permeates through the GO film barrier. The GO film was chemically reduced by the vapor of hydriodic acid and acetic acid (HI-AcOH, volume ratio of 1: 1) at 100 degrees C for 3 h, followed by annealing at 1100 degrees C for 0.5 h in an Ar atmosphere. The reduced graphene oxide (RGO) film had a sheet resistance of 562 Omega/square and a transparency of 63.7% at a typical wavelength of 550 nm, which is sufficient for many applications in optoelectronics, and this effective synergy reduction method advances the research on graphene-based electrodes.