• 文献标题:   The continuous synthesis and application of graphene supported palladium nanoparticles: a highly effective catalyst for Suzuki-Miyaura cross-coupling reactions
  • 文献类型:   Article
  • 作  者:   BRINKLEY KW, BURKHOLDER M, SIAMAKI AR, BELECKI K, GUPTON BF
  • 作者关键词:   flow chemistry, graphene, palladium, solid supported catalysi, suzukimiyaura crosscoupling
  • 出版物名称:   GREEN PROCESSING SYNTHESIS
  • ISSN:   2191-9542 EI 2191-9550
  • 通讯作者地址:   Virginia Commonwealth Univ
  • 被引频次:   5
  • DOI:   10.1515/gps-2015-0021
  • 出版年:   2015

▎ 摘  要

An efficient, sustainable, and continuous method for the preparation of graphene supported palladium nanoparticles (Pd/G) has been developed using microwave irradiation as a heating source for the metal deposition process. The Pd/G produced from this method was effective in Suzuki-Miyaura cross-coupling reactions with a broad range of substrates. When incorporated into a packed bed flow reactor, this ligand free catalyst system continued to demonstrate high reaction conversions with limited catalyst leaching in the reaction mixture (347 ppb palladium).