• 文献标题:   Solid-Phase Pyrolysis Synthesis of Highly Fluorescent Nitrogen/Sulfur Codoped Graphene Quantum Dots for Selective and Sensitive Diversity Detection of Cr(VI)
  • 文献类型:   Article, Early Access
  • 作  者:   BEZUNEH TT, FEREJA TH, LI HJ, JIN YD
  • 作者关键词:  
  • 出版物名称:   LANGMUIR
  • ISSN:   0743-7463
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1021/acs.langmuir.2c02966 EA JAN 2023
  • 出版年:   2023

▎ 摘  要

In this study, a simple one-step solid-phase pyrolysis synthesis procedure was employed to prepare N and S codoped highly fluorescent graphene quantum dots (N/S-GQDs). The as-synthesized quantum dot showed lambda excitation-dependent blue fluorescence (FL) emission with a relative quantum yield of about 22% and displayed good biocompatibility, high water dispersibility, and excellent stability under extreme conditions (i.e., ionic strength, pH, and temperature). The potential applicability of the as-synthesized quantum dot was tested by employing solution-and paper-based FL detection modes for Cr(VI) detection. The proposed solution-and paper-based FL sensors showed lower limit of detection (LOD) values of 0.01 and 0.4 mu M, respectively. The as-constructed paper-and solution-based FL sensors proved the feasibility of sensitive, cost-effective, and on-site detection of Cr(VI).