• 文献标题:   Preparation of graphene via wet ball milling and in situ reversible modification with the Diels-Alder reaction
  • 文献类型:   Article
  • 作  者:   XU JF, ZHAO XM, LIU FX, JIN L, CHEN GH
  • 作者关键词:  
  • 出版物名称:   NEW JOURNAL OF CHEMISTRY
  • ISSN:   1144-0546 EI 1369-9261
  • 通讯作者地址:   Huaqiao Univ
  • 被引频次:   0
  • DOI:   10.1039/c9nj05309c
  • 出版年:   2020

▎ 摘  要

Functionalized graphene (G-MA) was prepared by a facile wet ball milling strategy, which achieved exfoliation and functionalization of graphite simultaneously. The G-MA showed excellent dispersion in water and polar solvents. Thus, a G-MA coating was prepared from G-MA in mixed solvents (H2O-ethanol) without binder or surfactant. The scanning electron microscope (SEM) images of the G-MA coating exhibited a smooth and flat surface. The G-MA coating showed a conductivity of 769 S m(-1) at room temperature, and a big increase could be found at 2000 S m(-1) after thermal treatment under 200 degrees C for 2 h, indicating the restoration of the conjugated structure via the reverse Diels-Alder reaction. This synthetic method of functionalized graphene offers a powerful strategy for the reversible modification of the graphene electronic properties, which may expand their usage.