• 文献标题:   Sulfur dioxide sensing properties of MOF-derived ZnFe2O4 functionalized with reduced graphene oxide at room temperature
  • 文献类型:   Article, Early Access
  • 作  者:   ZHOU LJ, ZHANG XX, ZHANG WY
  • 作者关键词:   ternary metal oxide, znfe2o4 nanorod, reduced graphene oxide, so2 gas sensor
  • 出版物名称:   RARE METALS
  • ISSN:   1001-0521 EI 1867-7185
  • 通讯作者地址:   China Univ Petr East China
  • 被引频次:   1
  • DOI:   10.1007/s12598-020-01608-w EA OCT 2020
  • 出版年:  

▎ 摘  要

In this paper, ZnFe2O4 nanorods were prepared using Zn/Fe metal organic framework (MOF) as precursors, and ZnFe2O4/reduced graphene oxide (rGO) was prepared by hydrothermal method. The morphology and composition of the ZnFe2O4/rGO nanocomposite were characterized, and the results showed that the MOF-derived ZnFe2O4 nanorods are uniformly modified on the surface of rGO. The ZnFe2O4/rGO nanocomposite exhibits better SO2 gas sensing performance than the single ZnFe2O4 nanorods at room temperature. The sensing characteristics of single ZnFe2O4 film sensor, single rGO film sensor and ZnFe2O4/rGO composite film sensor at SO2 gas concentration (1 x 10(-6)-100 x 10(-6)) were tested. The response of ZnFe2O4/rGO composite sensor can reach 18.32% at room temperature. Compared with single ZnFe2O4 and rGO film sensors, the ZnFe2O4/rGO composite sensor has better transient response, good sensitivity and selectivity. In this work, the improvement of the sensor performance is not only due to the p-n heterostructure between ZnFe2O4 nanorods and rGO nanosheets, but also to the excellent electrical properties of rGO. It provides a new idea for the detection of SO2 at room temperature.