• 文献标题:   Noncovalently functionalized graphene oxide/graphene with imidazolium-based ionic liquids for adsorptive removal of dibenzothiophene from model fuel
  • 文献类型:   Article
  • 作  者:   DIZAJI AK, MORTAHEB HR, MOKHTARANI B
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS SCIENCE
  • ISSN:   0022-2461 EI 1573-4803
  • 通讯作者地址:   Chem Chem Engn Res Ctr Iran
  • 被引频次:   22
  • DOI:   10.1007/s10853-016-0237-5
  • 出版年:   2016

▎ 摘  要

Graphene (G) and graphene oxide (GO) were functionalized with 1-methyl-3-octyl-imidazolium hexafluorophosphate ([Omim][PF6]), 1-methyl-3-octyl-imidazolium tetrafluoroborate, and 1-methyl-3-octyl-imidazolium thiocyanate ionic liquids through a non-covalent functionalizing procedure. Different characterization techniques including XRD, AFM, FTIR, SEM/EDX, TGA, XPS, and RAMAN spectroscopy were used to verify the success of functionalization. The functionalized graphenes and graphene oxides were then used as adsorbents to remove dibenzothiophene from a model fuel having decane as the solvent. Among the prepared adsorbents, the functionalized graphene with the ionic liquid of [Omim][PF6] exhibited the highest adsorption capacity of 6.5 mg/g. The results showed that functionalization of graphene and graphene oxide improves their adsorption capacity in comparison to those of graphene (3.2 mg/g) and graphene oxide (2.25 mg/g).