• 文献标题:   Liquid-Solid-Solution Assembly of CoFe2O4/Graphene Nanocomposite as a High-Performance Lithium-Ion Battery Anode
  • 文献类型:   Article
  • 作  者:   ZHU YF, LV XB, ZHANG LL, GUO XD, LIU DJ, CHEN JJ, JI JY
  • 作者关键词:   liquidsolidsolution assemble, cofe2o4 nanoparticle, graphene, lithium ion batterie
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Sichuan Univ
  • 被引频次:   28
  • DOI:   10.1016/j.electacta.2016.08.057
  • 出版年:   2016

▎ 摘  要

CoFe2O4/graphene composites were fabricated via a novel one-pot liquid-solid-solution (LSS) hydrothermal process. Through ions electrostatic adsorption onto graphene sheets and oil microemulsion encapsulation, CoFe2O4 nanoparticles can be uniformly anchored on crumpled graphene sheets without aggregation, and the size distribution of CoFe2O4 particles can be controlled by the microemulsion shell in the range of 50-100 nm. With the synergistic effect between CoFe2O4 and graphene, the CoFe2O4/graphene hybrid exhibits a high reversible specific capacity of 1102 mAh g(-1) at 0.2 A g(-1) after 100 cycles, and a good cycling stability as well. Moreover, the composite has good rate capability. The specific capacity can reach a high value of 410 mAh g(-1) even under a high current density of 6.4 A g(-1) (corresponds to a charge time of similar to 230 s), indicating its promising application as an anode material for lithium ion batteries. a 2016 Elsevier Ltd. All rights reserved.