• 文献标题:   One-step electrochemical preparation of sulfonated graphene/polypyrrole composite and its application to supercapacitor
  • 文献类型:   Article
  • 作  者:   ZUO XP, ZHANG YL, SI L, ZHOU B, ZHAO B, ZHU LH, JIANG XQ
  • 作者关键词:   sulfonated graphene, polypyrrole, composite, supercapacitor, electrodeposition
  • 出版物名称:   JOURNAL OF ALLOYS COMPOUNDS
  • ISSN:   0925-8388 EI 1873-4669
  • 通讯作者地址:   Nanjing Normal Univ
  • 被引频次:   42
  • DOI:   10.1016/j.jallcom.2016.07.184
  • 出版年:   2016

▎ 摘  要

A sulfonated graphene/polypyrrole (s-G/PPy) composite was successfully prepared by a method of one-step electrodeposition using water soluble sulfonated graphene (s-G) and polypyrrole as the starting materials. The morphology, structure and thermal stability of s-G/PPy were characterized using transmission electron microscope, scanning electron microscope, thermogravimetric analysis, and Raman spectroscopy. The electrochemical performance of s-G/PPy is evaluated with galvanostatic charge/discharge, cyclic voltammetry and electrochemical impedance spectroscopy in 1 mol L-1 KCl. The composite exhibits high specific capacitance and good cycling stability. The specific capacitance of s-G/PPy is as high as 310 F g(-1) at a current density of 0.3 A g(-1) and retains 71% after 1500 cycles at a scan rate of 50 mV s(-1). The equivalent series resistance of s-G/PPy film is only 0.6 Omega. In addition, a s-G/PPy//s-G/PPy symmetric supercapacitor was also fabricated and in which the s-G/PPy showed specific capacitance still up to 253 F g(-1). (C) 2016 Elsevier B.V. All rights reserved.