• 文献标题:   Reduced graphene oxide supported TiO2 as high performance catalysts for oxygen reduction reaction
  • 文献类型:   Article
  • 作  者:   YU JM, LIU ZM, ZHAI LM, HUANG TZ, HAN JT
  • 作者关键词:   nonpreciousmetal catalyst, oxygen reduction reaction, n f codoped tio2, reduced graphene oxide
  • 出版物名称:   INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
  • ISSN:   0360-3199 EI 1879-3487
  • 通讯作者地址:   Univ Jinan
  • 被引频次:   15
  • DOI:   10.1016/j.ijhydene.2015.12.192
  • 出版年:   2016

▎ 摘  要

To overcome the shortcomings of high cost and rare sources of precious metal based catalysts, the catalytic characteristics of reduced graphene oxide (rGO) supported (N, F)-co doped TiO2 hybrid (TiO2/rGO) for oxygen reduction are investigated. Results show that the onset potential of oxygen reduction reaction (ORR) under the catalysis of TiO2/rGO is about -0.20 V (vs. Hg/Hg2Cl2). The corresponding electron transfer number of ORR is 3.98, which means that the ORR is major happened through a 4-electron process. TiO2/rGO catalyst has high catalytic for ORR and better stability than the commercial Pt/C catalytic performance in alkaline electrolyte. TiO2/rGO catalyst shows great promise as a high activity non precious metal catalyst for ORR. Copyright (C) 2016, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.