• 文献标题:   Electric Field Polarized Fe-N Functionalized Graphene Oxide Nanosheet Catalyst for Efficient Oxygen Reduction Reaction
  • 文献类型:   Article
  • 作  者:   ZHAO R, XIA JX, ADAMAQUAYE P, ZHAO GL
  • 作者关键词:   electric field polarization, electrocatalyst, fe n doped graphene, oxygen, reduction
  • 出版物名称:   CHEMISTRYSELECT
  • ISSN:   2365-6549
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1002/slct.202200616
  • 出版年:   2022

▎ 摘  要

Low-cost noble-metal-free electrocatalysts for oxygen reduction reaction (ORR) are useful for future energy storage and conversion devices, and other technologies. In this work, iron (Fe)-nitrogen (N) functionalized graphene oxide (Fe-N-GO) nanosheets have been synthesized and studied for ORR properties in alkaline solution. We utilized a multi-layer/multi-polarization method to study the DC electric field polarization effect on the electrocatalytic properties of the Fe-N-GO catalyst. The poling effect with DC electric field was created on the catalyst ink drop-casted on a polished glassy carbon working electrode, resulting in more compact electrocatalyst electrode. Compared to the commercial Pt/C catalyst, the polarized Fe-N-GO catalyst exhibited similar ORR catalytic activity along with superior stability in alkaline media.